Version2.2 2021-02-15T10:56:57Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 13-Jan-2021 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE c1cc([nH+]cc1O)C[C@@H](C(=O)N[C@@H]([C@@H]2[C@H]([C@H]([C@H](O2)n3ccc(=O)[nH]c3=O)O)O)C(=O)[O-])[NH3+] C48999385 RHF 6-31G(d) (6D,7F) c1cc([nH+]cc1O)C[C@@H](C(=O)N[C@@H]([C@@H]2[C@H]([C@H]([C@H](O2)n3ccc(=O)[nH]c3=O)O)O)C(=O)[O-])[NH3+] C01[X(C18H22N5O9)] 156 C1 524 O=c1ccn(c(=O)[nH]1)[C@H]1O[C@@H]([C@H]([C@H]1O)O)[C@@H](C(=O)[O-])NC(=O)[C@H](Cc1ccc(c[nH+]1)O)[NH3+] O=c1ccn(c(=O)[nH]1)[C@H]1O[C@@H]([C@H]([C@H]1O)O)[C@@H](C(=O)[O-])NC(=O)[C@H](Cc1ccc(c[nH+]1)O)[NH3+] [NH3+][C@@H](Cc1ccc(O)c[nH+]1)C(=O)N[C@@H]([C@H]2O[C@@H]([C@H](O)[C@@H]2O)N3C=CC(=O)NC3=O)C([O-])=O InChIKey=CHWSHTKKKFFZNQ-QHVJXGMISA-O InChI=1S/C18H21N5O9/c19-9(5-7-1-2-8(24)6-20-7)15(28)22-11(17(29)30)14-12(26)13(27)16(32-14)23-4-3-10(25)21-18(23)31/h1-4,6,9,11-14,16,24,26-27H,5,19H2,(H,22,28)(H,29,30)(H,21,25,31)/p+1/t9-,11-,12-,13+,14+,16-/m0/s1 InChI=1/C18H21N5O9/c19-9(5-7-1-2-8(24)6-20-7)15(28)22-11(17(29)30)14-12(26)13(27)16(32-14)23-4-3-10(25)21-18(23)31/h1-4,6,9,11-14,16,24,26-27H,5,19H2,(H,22,28)(H,29,30)(H,21,25,31)/p+1/t9-,11-,12-,13+,14+,16-/m0/s1/fC18H22N5O9/h19-22H/q+1 c1cc([nH+]cc1O)C[C@@H](C(=O)N[C@@H]([C@@H]2[C@H]([C@H]([C@H](O2)n3ccc(=O)[nH]c3=O)O)O)C(=O)[O-])[NH3+] C01[X(C18H22N5O9)] 156 C01 524 O=c1ccn(c(=O)[nH]1)[C@H]1O[C@@H]([C@H]([C@H]1O)O)[C@@H](C(=O)[O-])NC(=O)[C@H](Cc1ccc(c[nH+]1)O)[NH3+] O=C1C=CN([C]([O])N1)[C@H]1O[C@@H]([C@H]([C@H]1O)O)[C@@H]([C]([O])=O)[NH][C](=O)[C@H](C[C]1[CH][CH][C]([CH][NH]1)O)[NH3] [NH3][C@@H](C[C]1[CH][CH][C](O)[CH]N1)C(=O)N[C@@H]([C@H]2O[C@@H]([C@H](O)[C@@H]2O)N3C=CC(=O)N[C]3[O])C([O])=O InChIKey=KOBPIYHHQBRURU-QHVJXGMISA-N InChI=1S/C18H22N5O9/c19-9(5-7-1-2-8(24)6-20-7)15(28)22-11(17(29)30)14-12(26)13(27)16(32-14)23-4-3-10(25)21-18(23)31/h1-4,6,9,11-14,16,20,24,26-27H,5H2,19H3,(H,22,28)(H,21,25,31)/t9-,11-,12-,13+,14+,16-/m0/s1 InChI=1/C18H22N5O9/c19-9(5-7-1-2-8(24)6-20-7)15(28)22-11(17(29)30)14-12(26)13(27)16(32-14)23-4-3-10(25)21-18(23)31/h1-4,6,9,11-14,16,20,24,26-27H,5H2,19H3,(H,22,28)(H,21,25,31)/t9-,11-,12-,13+,14+,16-/m0/s1/f/h21-22H 3644.2686994390 -1640.265479 1-A 12542.2206 118 406 524 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -20.70727 -20.68279 -20.67433 -20.67024 -20.65235 -20.64564 -20.61822 -20.59671 -20.59646 -15.87489 -15.79358 -15.72442 -15.71986 -15.70528 -11.51048 -11.50601 -11.48865 -11.46225 -11.45631 -11.44636 -11.44074 -11.43127 -11.43051 -11.41868 -11.40837 -11.40703 -11.38850 -11.38504 -11.37769 -11.37603 -11.37516 -11.31483 -1.56203 -1.54397 -1.53604 -1.51680 -1.49584 -1.49351 -1.48692 -1.48189 -1.47625 -1.45504 -1.39410 -1.38816 -1.37191 -1.33157 -1.26814 -1.25129 -1.19221 -1.16852 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1.7454 2.0906 1.7204 1.8411 1.5399 3.4851 2.0665 1.3548 3.0109 1.7197 1.6217 1.9239 2.3003 2.8804 1.3925 1.7731 2.2979 1.6970 2.2148 1.8931 1.8008 1.7744 2.2319 1.8580 1.9335 1.8916 2.0980 2.2974 1.9234 2.6962 2.0140 2.4623 2.8898 4.1582 2.9498 2.5590 2.3820 1.8166 2.9560 1.9947 3.2681 3.3837 5.1398 2.0110 9.6434 2.0994 11.6721 7.5752 15.4091 6.1880 16.8866 23.6177 4.7707 6.5556 6.7648 6.8618 7.0005 6.9720 7.0783 7.2456 7.4201 7.3914 7.5295 7.6335 7.6556 7.9733 7.7027 8.5878 9.1020 9.3333 9.3860 9.3370 10.3215 10.6670 4.5116 1.7383 3.0520 2.5697 15.6252 2.3010 16.4868 4.8233 2.2328 10.7405 0.5738 7.3199 0.9413 7.4168 8.0589 9.6842 20.4716 1.6995 3.2472 11.2169 2.0996 29.9631 29.3920 48.5435 11.2269 2.8583 24.8189 9.9457 2.9124 4.4357 26.8493 43.6725 5.9024 31.3964 26.7719 20.5210 5.7879 81.5103 181.8061 10.9644 5.0177 12.7261 25.4249 24.5074 5.4217 5.8247 223.0378 10.2339 109.5940 28.0491 103.6395 88.5954 68.4269 1.5587 22.6326 21.1073 25.8575 15.6333 29.7803 73.9439 47.4938 14.5235 23.8397 72.6380 24.3070 28.1770 42.9485 24.8056 4.7911 15.8765 36.4749 35.6377 33.5595 0.4159 68.2556 63.6839 5.5265 10.6854 2.2281 23.6185 119.7943 54.8977 18.0575 52.6427 64.3131 63.7233 30.4252 187.3718 46.6294 275.3838 80.2902 6.0157 5.3818 90.6541 3.8609 8.2345 60.7013 57.9663 266.8710 92.1786 275.7346 3.0743 37.6084 17.2185 26.7009 13.5392 6.8815 103.3573 35.1444 55.0543 1.0962 71.6717 11.0036 65.1776 49.9482 53.3296 21.5659 189.1934 0.9731 3.0358 116.6959 432.8169 96.1681 278.4423 207.0868 56.5882 12.7885 54.2687 169.3406 325.5146 939.0205 356.2301 436.4915 799.9757 1825.8252 17.4270 37.3241 18.8107 5.8276 2.6598 0.0806 2.4660 2.8580 2.1786 0.4922 1.9052 12.2397 14.3299 152.9369 147.1311 102.2354 50.2226 110.6150 783.3811 153.3199 120.6616 3.1770 0.8404 3.0553 0.7893 0.5595 0.8830 0.2157 1.4288 2.2282 3.2074 1.9700 0.3176 0.8792 0.8940 0.4619 0.6559 1.2727 1.3878 0.2981 0.2559 0.4705 0.9529 1.6064 1.9904 1.0017 2.4153 0.8410 1.1298 2.0177 2.8011 0.8668 1.0289 0.8011 0.9358 1.5548 0.6817 1.3206 1.5558 3.9821 0.7107 1.5348 1.7176 2.7015 1.1140 2.1291 1.9502 5.1738 0.5539 5.7890 2.3104 2.3764 5.5864 0.9532 1.8424 3.9761 2.8582 4.5471 7.3585 0.9992 0.8322 2.6920 1.5223 1.7347 2.0237 7.6766 25.4658 10.6647 7.2079 2.1768 6.8297 6.8715 1.0252 3.5253 3.7796 2.7558 1.9563 2.2041 2.5711 4.5517 3.0508 4.2885 4.7850 4.8719 3.2024 4.6039 3.6727 4.0006 3.9818 5.0687 3.7171 2.4936 2.5342 5.9969 2.5135 31.7102 13.2671 2.6239 6.6053 3.4055 2.2229 5.1744 4.7277 9.6423 3.1651 4.9549 4.6026 3.3556 2.6135 7.9219 2.0274 4.9996 1.8295 1.0683 6.2267 8.5106 15.0085 6.2523 1.1200 3.9153 9.8076 6.5252 6.5099 13.6742 3.4977 29.1319 7.0729 22.1370 4.3735 42.6583 17.2410 2.9155 19.2720 8.8182 72.5409 63.1184 102.8231 86.8492 54.0494 57.6370 70.6559 8.2732 33.5141 55.9609 26.8975 109.4964 89.2438 38.8057 37.9959 37.5123 60.3073 46.6070 24.7036 67.6439 117.2582 63.6302 105.6090 0.7247 0.7326 0.7239 0.6618 0.6995 0.7431 0.7329 0.7393 0.7155 0.7204 0.7071 0.7001 0.5829 0.6585 0.3789 0.6556 0.4939 0.4327 0.6899 0.6234 0.7495 0.1466 0.7332 0.3823 0.4960 0.2618 0.2468 0.1537 0.6480 0.4325 0.7180 0.5187 0.6524 0.5546 0.2913 0.6359 0.5747 0.5941 0.6897 0.2066 0.2696 0.3813 0.1288 0.3621 0.6597 0.3611 0.6820 0.6261 0.6716 0.5731 0.5585 0.6871 0.6238 0.2656 0.5282 0.6462 0.3087 0.0835 0.7399 0.6769 0.3564 0.7075 0.1408 0.7465 0.3583 0.0408 0.1975 0.0421 0.5430 0.2804 0.5192 0.6237 0.7089 0.4552 0.7489 0.5706 0.4214 0.4928 0.7280 0.6115 0.3800 0.7342 0.3151 0.3771 0.6901 0.7430 0.5251 0.4250 0.2114 0.7462 0.6744 0.6133 0.6887 0.5424 0.4534 0.1480 0.7303 0.4437 0.2430 0.5690 0.3972 0.2546 0.5264 0.7494 0.3029 0.4742 0.6970 0.4809 0.3487 0.7099 0.7462 0.7470 0.6837 0.4718 0.5924 0.2742 0.6458 0.7500 0.6936 0.7284 0.5450 0.3977 0.7049 0.6596 0.3127 0.6408 0.5635 0.7493 0.1680 0.4456 0.7423 0.5054 0.2948 0.2986 0.3672 0.1546 0.3185 0.2967 0.3982 0.2213 0.6197 0.2100 0.5092 0.1266 0.2139 0.3158 0.2239 0.2099 0.0395 0.2019 0.6970 0.1753 0.1500 0.2798 0.2374 0.3095 0.8404 0.8457 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0.4800 0.3658 0.3470 0.0759 0.3360 0.8215 0.2983 0.2609 0.4373 0.3837 0.4727 298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 6 6 6 7 1 6 6 8 6 6 1 6 8 7 6 1 6 1 6 1 6 1 6 1 8 7 6 6 6 8 7 1 6 8 8 8 6 8 8 7 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 12.00000 14.00307 1.00783 12.00000 12.00000 15.99491 12.00000 12.00000 1.00783 12.00000 15.99491 14.00307 12.00000 1.00783 12.00000 1.00783 12.00000 1.00783 12.00000 1.00783 12.00000 1.00783 15.99491 14.00307 12.00000 12.00000 12.00000 15.99491 14.00307 1.00783 12.00000 15.99491 15.99491 15.99491 12.00000 15.99491 15.99491 14.00307 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 9937.3479 15179.8240 20763.1525 0.99954 -0.02782 0.01173 0.02789 0.99959 -0.00570 -0.01156 0.00603 0.99991 1 0.00872 0.00571 0.00417 0.18161 0.11889 0.08692 37.42 49.56 62.48 78.68 89.12 102.96 120.41 124.19 145.45 173.93 182.46 194.23 228.67 240.22 264.67 281.36 292.38 298.18 320.17 374.87 380.32 389.98 397.73 416.78 431.43 464.85 498.14 503.17 551.15 570.25 575.05 607.36 641.61 646.73 651.72 671.20 696.53 725.70 742.58 808.32 839.73 848.37 868.33 872.73 912.57 929.89 948.25 990.29 1007.77 1031.27 1065.52 1073.54 1099.25 1124.25 1153.49 1156.76 1184.55 1207.08 1233.12 1262.26 1280.59 1296.23 1298.35 1314.87 1342.54 1356.48 1377.32 1407.43 1439.73 1446.24 1467.72 1496.43 1503.57 1543.73 1575.14 1581.56 1606.40 1609.13 1621.64 1627.32 1647.55 1699.89 1722.12 1739.72 1749.46 1760.20 1769.60 1817.00 1822.52 1860.85 1876.59 1918.80 1922.23 1941.36 1945.37 1951.45 1960.18 1979.72 2023.71 2040.25 2045.56 2061.61 2070.73 2103.60 2130.07 2131.56 2139.52 2154.32 2173.74 2191.31 2201.38 2219.56 2233.59 2245.99 2250.56 2260.66 2273.14 2277.56 2301.14 2340.47 2346.95 2383.53 2391.68 2461.25 2554.53 2568.23 2586.17 2643.19 2658.12 2675.10 2728.18 2756.01 2817.36 2908.80 3801.02 4644.45 4673.32 4708.58 4742.46 4748.30 4762.31 4834.36 4884.09 4886.56 4911.97 4948.59 4950.01 5054.03 5062.14 5310.74 5404.38 5515.09 5529.08 5541.21 5833.29 5924.94 0.464156 0.490570 0.491514 0.407333 -1639.801322 -1639.774909 -1639.773965 -1639.858146 2.823445D-04 MUNgauss RevisionA2.1 retrievium 15-Feb-2021 DUDE c1cc([nH+]cc1O)C[C@@H](C(=O)N[C@@H]([C@@H]2[C@H]([C@H]([C@H](O2)n3ccc(=O)[nH]c3=O)O)O)C(=O)[O-])[NH3+] C48999385 RHF 6-31G(d) (6D,10F) C1 452.141753 |X|Y|Z| 65.192757 83.533616 36.249163 58.226346 22 6 7 8 17 4 1 |36.858105| |13.719571|36.858105| |7.960393|13.830316|36.858105| |7.074424|8.200148|14.281492|53.358707| |5.076831|5.811862|9.288574|24.423068|0.500000| |8.031724|6.982474|8.108108|19.595821|0.258245|36.858105| |13.737079|7.913340|6.868883|11.034521|0.160249|13.719687|36.858105| |8.108553|5.269010|4.647796|7.257903|0.119622|8.003795|14.371155|73.516695| |4.992159|7.453915|12.558804|10.596071|0.206040|5.143467|4.443306|6.034417|36.858105| |4.116079|5.582052|7.365239|7.634339|0.156686|4.166856|3.719472|5.294363|12.269146|36.858105| |4.416745|6.003692|6.912070|7.022615|0.135093|4.072310|3.836327|5.485763|8.695609|17.620597|0.500000| |3.508303|4.295632|5.637570|7.116904|0.163038|4.013111|3.419673|5.007919|7.335371|12.293581|0.240011|36.858105| |2.921241|3.485060|4.402455|5.713488|0.133893|3.342145|2.872295|4.321977|5.787483|8.124949|0.167781|15.856319|73.516695| |3.695590|4.279784|5.436045|7.520486|0.170463|4.466830|3.752299|5.529141|5.790539|7.771217|0.197053|14.332044|14.944126|53.358707| |3.218372|3.510239|4.354036|6.696492|0.162476|4.255934|3.461752|5.294527|4.411216|5.056820|0.128047|7.809557|11.669169|17.622995|36.858105| |2.764812|3.032382|3.698011|5.489770|0.132822|3.501641|2.921665|4.547871|3.950119|4.604222|0.114270|7.259711|12.929377|12.471361|17.614378|0.500000| |3.038537|3.152954|3.638385|5.552756|0.123924|3.875056|3.317276|5.296781|3.485914|3.936975|0.107706|5.212640|7.990834|10.775671|12.488277|0.245599|36.858105| |2.780872|2.913673|3.280892|4.766137|0.103875|3.302002|2.938758|4.734115|3.235290|3.811731|0.106744|5.016079|7.864193|9.840570|8.927224|0.216909|17.603595|0.500000| |2.605001|2.627879|2.970211|4.617896|0.103468|3.369297|2.906865|4.834924|2.829984|3.045095|0.082555|3.809110|6.255262|6.758503|7.301019|0.180810|12.381342|0.247177|36.858105| |2.587680|2.611733|3.001968|4.797641|0.110871|3.497297|2.931622|4.864410|2.862314|2.987912|0.079201|3.728751|6.242201|6.360397|7.104639|0.180782|8.757236|0.177318|17.713158|0.500000| |2.664747|2.587700|2.817023|4.381950|0.093706|3.385476|3.030341|5.239744|2.584010|2.721598|0.075892|3.195574|5.143775|5.542925|5.126220|0.123289|7.941534|0.181016|12.379313|0.244441|36.858105| |2.486196|2.384792|2.580318|4.049117|0.086664|3.189572|2.862819|5.068592|2.359889|2.428613|0.067198|2.797491|4.581162|4.660419|4.240887|0.105290|5.702611|0.133938|8.654907|0.219781|17.563887|0.500000| |3.368445|3.195727|3.464968|5.534671|0.114515|4.453812|3.962728|6.777758|3.024350|3.134426|0.088736|3.590764|5.514956|6.455742|5.600473|0.123549|8.197931|0.174135|8.066307|0.188858|12.468338|0.244395|36.858105| |3.565663|3.334143|3.679320|6.217515|0.130217|5.242998|4.416702|7.571937|3.138271|3.121947|0.086529|3.538381|5.466711|6.172898|5.452580|0.120184|6.781593|0.141676|7.003450|0.193097|8.956277|0.224315|17.752317|0.500000| |3.639062|3.633219|4.057427|6.284797|0.131102|4.657659|4.075875|6.518289|3.609002|3.941124|0.112764|4.723715|6.895271|9.548743|7.980204|0.159135|13.424905|0.260484|8.025671|0.179021|8.170845|0.162370|13.516937|0.259501|73.516695| |3.482347|3.158951|3.230977|4.972944|0.097578|4.170290|4.073275|7.401456|2.762654|2.837663|0.082770|3.072810|4.724931|5.258175|4.110852|0.094965|5.371305|0.131256|5.132963|0.125198|7.458349|0.176374|13.137334|0.259906|14.566629|53.358707| |3.074921|2.842019|2.844494|4.166405|0.081678|3.349690|3.381877|6.122071|2.505522|2.647724|0.078811|2.839745|4.409467|4.770352|3.593256|0.085944|4.711719|0.126832|4.425803|0.104636|6.076368|0.142279|7.697128|0.159106|11.541640|18.623765|36.858105| |2.947690|2.673637|2.589077|3.707804|0.071505|3.002128|3.169883|5.930303|2.277712|2.381479|0.071575|2.472975|3.875581|3.995054|2.922348|0.071479|3.578676|0.098090|3.383248|0.083119|4.316928|0.108468|5.134587|0.119434|8.166945|10.825369|14.345291|36.858105| |3.163282|2.749784|2.598142|3.741559|0.070803|3.138009|3.460221|6.875546|2.234185|2.265602|0.067767|2.298151|3.607306|3.633357|2.643498|0.064681|3.085834|0.082279|2.944806|0.075175|3.661017|0.096364|4.464500|0.112764|6.972319|9.197658|7.910958|13.099514|36.858105| |2.898298|2.516520|2.341628|3.317732|0.062671|2.757630|3.090711|6.219041|2.032099|2.049063|0.061312|2.048570|3.248358|3.164356|2.282294|0.056713|2.594972|0.069957|2.488401|0.064349|2.989726|0.079991|3.493976|0.090685|5.631384|6.474902|5.400535|8.030610|16.016041|73.516695| |3.676373|3.084810|2.932892|4.373572|0.081834|3.859551|4.298922|9.018841|2.447291|2.419633|0.071442|2.457523|3.829364|3.913562|2.886065|0.069414|3.324309|0.085193|3.187193|0.083190|3.993660|0.106976|5.235254|0.140355|7.737740|11.230942|7.167101|8.019360|13.608832|15.086654|53.358707| |3.730458|3.045599|2.848391|4.242105|0.078611|3.814581|4.408713|9.988101|2.359956|2.287520|0.067166|2.288357|3.590398|3.566462|2.617622|0.063572|2.917155|0.074726|2.814327|0.075074|3.407177|0.093356|4.308477|0.121303|6.550053|8.098834|5.209313|5.806861|9.318769|13.911737|25.956077|0.500000| |3.948334|3.368257|3.337929|5.212802|0.098646|4.714494|4.891394|9.725033|2.749931|2.711991|0.078956|2.826556|4.356184|4.646194|3.531219|0.082543|4.162974|0.101869|3.992860|0.104421|5.191976|0.136960|7.864995|0.218374|10.350714|18.908359|7.966624|6.780910|7.690737|9.615111|19.134292|0.263884|36.858105| |4.345010|3.620801|3.650854|6.020191|0.113011|5.918374|5.924700|12.271212|2.926859|2.781486|0.079296|2.884659|4.455028|4.671392|3.597605|0.083722|4.003064|0.095148|3.877509|0.106781|4.736219|0.129880|6.962151|0.237295|9.502751|11.391117|5.417263|4.738120|5.351501|7.560303|11.584457|0.218230|15.682450|73.516695| |2.415527|2.353092|2.501279|3.740737|0.078471|2.857101|2.660655|4.643884|2.329245|2.506061|0.071230|2.895467|4.700363|4.912985|4.224928|0.106079|6.337191|0.173931|7.943871|0.160590|13.676508|0.258586|7.881906|0.160156|11.537300|8.998553|6.811932|4.793310|3.767937|5.495808|5.181834|0.089228|4.552953|6.971919|73.516695| |2.221734|2.263025|2.521428|3.780455|0.083965|2.720119|2.412869|4.046675|2.476642|2.716103|0.073815|3.381578|5.796893|5.665031|5.608660|0.159890|7.932217|0.220197|13.574589|0.257629|7.825813|0.177451|5.315926|0.129645|9.744151|5.427998|3.758768|2.995606|2.580656|3.963391|3.664018|0.066730|3.193690|5.432977|12.878068|73.516695| |3.500121|3.764053|4.898376|8.582198|0.241994|5.353957|3.960433|5.953222|4.711285|4.675396|0.114736|6.243318|9.687243|10.706251|12.240189|0.242933|7.327538|0.150682|5.995270|0.192418|4.659378|0.115649|5.331117|0.166292|11.316388|5.385404|3.279629|2.727504|2.574986|3.975451|3.973212|0.075216|3.636873|7.066822|6.498644|7.970531|36.858105| |3.354827|3.413888|4.195313|7.564097|0.194431|5.396712|3.986786|6.256616|3.819519|3.687996|0.094359|4.510300|7.204319|7.558412|7.952835|0.174606|6.718129|0.135990|6.597600|0.236957|5.394350|0.140375|6.159565|0.216480|11.186320|5.947223|3.455580|2.847013|2.718979|4.163865|4.299992|0.081454|4.063245|8.192045|7.016665|8.224144|15.712337|73.516695| |3.688992|4.175636|5.877005|10.256247|0.349742|5.558640|4.041300|5.872057|6.059143|5.499950|0.125793|7.029965|11.085354|9.832758|8.062041|0.190269|5.178559|0.118545|4.313677|0.133096|3.579686|0.091143|4.085901|0.125669|8.533098|4.493035|2.815961|2.424149|2.332315|3.668163|3.577628|0.069110|3.162397|6.201439|5.277050|6.255274|15.125473|15.321427|73.516695| 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