Version2.1 2020-12-17T06:29:06Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 04-Nov-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE Cc1c(c(on1)C)S(=O)(=O)N2CCC[C@@H](C2)C(=O)Nc3ccc(cc3)Oc4ccccc4Cl C11513700 RHF 6-31G(d) (6D,7F) Cc1c(c(on1)C)S(=O)(=O)N2CCC[C@@H](C2)C(=O)Nc3ccc(cc3)Oc4ccccc4Cl C01[X(C23H24Cl1N3O5S1)] 165 C1 551 O=C([C@H]1CCCN(C1)S(=O)(=O)c1c(C)noc1C)Nc1ccc(cc1)Oc1ccccc1Cl O=C([C@H]1CCCN(C1)S(=O)(=O)c1c(C)noc1C)Nc1ccc(cc1)Oc1ccccc1Cl Cc1onc(C)c1[S](=O)(=O)N2CCC[C@@H](C2)C(=O)Nc3ccc(Oc4ccccc4Cl)cc3 InChIKey=OZZGNGYXYCHBCP-KRWDZBQOSA-N InChI=1S/C23H24ClN3O5S/c1-15-22(16(2)32-26-15)33(29,30)27-13-5-6-17(14-27)23(28)25-18-9-11-19(12-10-18)31-21-8-4-3-7-20(21)24/h3-4,7-12,17H,5-6,13-14H2,1-2H3,(H,25,28)/t17-/m0/s1 InChI=1/C23H24ClN3O5S/c1-15-22(16(2)32-26-15)33(29,30)27-13-5-6-17(14-27)23(28)25-18-9-11-19(12-10-18)31-21-8-4-3-7-20(21)24/h3-4,7-12,17H,5-6,13-14H2,1-2H3,(H,25,28)/t17-/m0/s1/f/h25H Cc1c(c(on1)C)S(=O)(=O)N2CCC[C@@H](C2)C(=O)Nc3ccc(cc3)Oc4ccccc4Cl C01[X(C23H24Cl1N3O5S1)] 165 C01 551 O=C([C@H]1CCCN(C1)S(=O)(=O)c1c(C)noc1C)Nc1ccc(cc1)Oc1ccccc1Cl O=C([C@H]1CCCN(C1)S(=O)(=O)[C]1[C](C)ON=[C]1C)N[C]1[CH][CH][C]([CH][CH]1)O[C]1[CH][CH][CH][CH][C]1Cl C[C]1ON=C(C)[C]1[S](=O)(=O)N2CCC[C@@H](C2)C(=O)N[C]3[CH][CH][C]([CH][CH]3)O[C]4[CH][CH][CH][CH][C]4Cl InChIKey=OZZGNGYXYCHBCP-KRWDZBQOSA-N InChI=1S/C23H24ClN3O5S/c1-15-22(16(2)32-26-15)33(29,30)27-13-5-6-17(14-27)23(28)25-18-9-11-19(12-10-18)31-21-8-4-3-7-20(21)24/h3-4,7-12,17H,5-6,13-14H2,1-2H3,(H,25,28)/t17-/m0/s1 InChI=1/C23H24ClN3O5S/c1-15-22(16(2)32-26-15)33(29,30)27-13-5-6-17(14-27)23(28)25-18-9-11-19(12-10-18)31-21-8-4-3-7-20(21)24/h3-4,7-12,17H,5-6,13-14H2,1-2H3,(H,25,28)/t17-/m0/s1/f/h25H 3543.2573349284 -2279.4896782 1-A 33002.0983 128 423 551 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1389.77 1401.05 1408.58 1413.52 1497.95 1507.36 1514.26 1541.79 1543.80 1551.50 1595.12 1597.96 1600.36 1603.44 1638.03 1643.96 1645.26 1664.17 1671.19 1680.98 1692.65 1701.75 1719.69 1727.43 1745.66 1762.64 1796.37 1810.91 1828.11 1841.24 1861.64 1873.21 1885.01 1899.94 1904.34 1932.70 1972.00 1996.15 2035.60 2044.33 2058.84 2059.90 2084.07 2088.48 2108.80 2130.46 2162.04 2178.47 2203.87 2208.37 2233.62 2249.31 2252.77 2278.37 2279.84 2318.24 2330.87 2335.06 2339.32 2346.31 2348.54 2364.93 2381.03 2390.33 2400.72 2432.60 2470.03 2476.92 2564.76 2579.22 2589.86 2615.19 2623.14 2811.03 4564.29 4623.43 4629.95 4635.51 4643.44 4645.72 4660.56 4680.53 4701.78 4734.29 4760.31 4793.80 4800.77 4808.03 4823.45 4848.55 4849.10 4873.06 4877.46 4883.54 4895.61 4910.34 4989.66 5590.06 0.482447 0.511124 0.512068 0.414586 -2279.007231 -2278.978554 -2278.977610 -2279.075093 3.269596D-04 MUNgauss RevisionA2.0 retrievium 17-Dec-2020 DUDE Cc1c(c(on1)C)S(=O)(=O)N2CCC[C@@H](C2)C(=O)Nc3ccc(cc3)Oc4ccccc4Cl C11513700 RHF 6-31G(d) (6D,10F) C1 489.112521 |X|Y|Z| 46.435063 33.158469 172.471265 64.276529 27 6 7 8 16 21 3 2 1 |36.858105| |12.722165|36.858105| |7.147233|13.204107|36.858105| |5.181730|8.647808|14.043419|36.858105| |5.348468|8.948252|8.781972|14.535333|73.516695| |7.915966|14.883475|8.532484|8.632228|24.676628|53.358707| |3.699402|5.161883|7.232195|12.772862|14.246954|7.225103|36.858105| |5.448594|6.626394|10.890395|6.812474|8.739749|6.602927|5.431338|388.023441| |3.989802|4.857505|7.434612|6.256790|7.857065|5.465286|6.081388|94.762069|73.516695| |6.067803|6.107917|7.441697|4.993094|7.267210|5.975214|4.020456|94.842140|13.612537|73.516695| |4.616102|5.173362|6.932264|5.195800|7.237159|5.514178|4.483188|82.628546|13.760697|13.746844|53.358707| |3.686061|4.297742|5.669331|5.019014|6.997888|5.005433|4.814821|50.830462|11.615088|8.873074|17.706674|36.858105| |3.009223|3.286084|3.946309|3.583931|5.359096|3.934644|3.527116|34.519362|8.214154|7.004633|10.636566|12.487244|36.858105| |3.078972|3.191225|3.583110|3.171393|4.957301|3.800141|2.977845|30.030646|6.633357|6.625829|9.029687|7.543885|12.465442|36.858105| |3.621050|3.558831|3.905821|3.251651|5.094629|4.058768|2.918396|34.524924|7.049008|8.224800|10.640204|6.510465|7.566601|12.394571|36.858105| |3.315473|3.247147|3.617965|3.023407|4.697433|3.710342|2.765589|33.894672|7.187458|8.403154|9.727945|5.791118|6.880793|8.857060|17.540673|0.500000| |5.007248|4.971657|5.569818|4.234960|6.469289|5.282627|3.555589|50.749703|8.886073|11.716187|17.725516|7.738229|6.530996|7.559028|12.432746|0.248519|36.858105| |3.409004|3.178251|3.257738|2.767811|4.531611|3.708599|2.467600|26.459571|5.487197|6.681849|6.868523|4.421792|4.936537|7.604073|12.510499|0.245044|7.644849|36.858105| |3.557515|3.279644|3.235813|2.783020|4.676522|3.889611|2.448973|24.585698|5.078641|6.137698|6.111499|4.067335|4.314190|6.261322|8.027601|0.163285|6.634401|15.868123|73.516695| |2.903783|2.681652|2.743407|2.366155|3.895388|3.172381|2.147509|22.524335|4.839480|5.879638|5.467862|3.559748|4.041711|5.601127|7.843015|0.211988|5.349286|14.026745|14.956724|53.358707| |2.563610|2.339379|2.338742|2.054430|3.450597|2.825054|1.873564|18.528203|4.053076|4.878269|4.251300|2.836348|3.145429|4.081863|5.007870|0.135840|3.940367|7.619469|11.570613|18.372756|36.858105| |2.542217|2.296555|2.240669|1.987202|3.400868|2.813173|1.800928|17.085834|3.726780|4.469862|3.841170|2.597705|2.805990|3.583384|4.193795|0.108099|3.550635|6.259616|11.689885|10.490094|13.702137|36.858105| |2.205758|1.998260|1.940157|1.745228|3.014069|2.485599|1.595555|14.623367|3.245297|3.833771|3.192095|2.185332|2.341602|2.863902|3.222695|0.085372|2.829498|4.306427|7.984943|6.970895|7.939092|13.745250|36.858105| |1.985463|1.812753|1.779353|1.607240|2.761069|2.257643|1.484258|13.583789|3.058710|3.578668|2.933778|2.012427|2.171387|2.596734|2.899561|0.079583|2.534130|3.672540|6.429284|6.194614|6.861114|7.927066|13.805626|36.858105| |1.994594|1.832470|1.825900|1.641010|2.785791|2.262553|1.522992|14.262277|3.228500|3.774991|3.101091|2.114874|2.314299|2.764088|3.126278|0.088740|2.661589|3.889539|6.400042|7.062781|7.898006|6.853387|7.960641|13.784671|36.858105| |2.232156|2.053471|2.068909|1.836598|3.081359|2.500203|1.697930|16.513916|3.700730|4.376751|3.685003|2.481233|2.759396|3.393961|3.988915|0.115271|3.234276|5.154396|7.895837|10.852853|13.688253|7.938063|6.915824|7.980326|13.793066|36.858105| |1.773586|1.625006|1.588806|1.449423|2.507238|2.045820|1.345479|11.996069|2.728636|3.155310|2.544405|1.759085|1.879706|2.192602|2.399994|0.066043|2.151479|2.912726|5.171557|4.667458|4.594311|5.215473|7.996978|13.895598|7.997691|5.234423|73.516695| |1.607916|1.492980|1.467262|1.352418|2.342334|1.895818|1.266444|11.024229|2.533621|2.863973|2.338989|1.643151|1.767263|2.045179|2.178107|0.059811|1.949245|2.588534|4.615895|4.053258|3.800342|4.227345|5.864509|8.029711|5.910408|4.255736|25.035269|36.858105| |1.584856|1.488814|1.474598|1.365816|2.358159|1.894842|1.286725|11.091654|2.560908|2.845163|2.381625|1.696786|1.851564|2.157722|2.246468|0.061374|1.978017|2.664917|4.749724|4.150052|3.834348|4.206165|5.454751|6.707739|5.452554|4.216031|13.997858|13.742055|36.858105| |1.432623|1.358175|1.348678|1.260902|2.182175|1.742486|1.196905|10.086079|2.350970|2.568549|2.151629|1.550109|1.689700|1.937200|1.978716|0.054092|1.759323|2.285178|4.084558|3.467190|3.043531|3.271666|3.952144|4.509926|3.965288|3.284854|9.236067|7.928848|13.745054|36.858105| |1.329476|1.258621|1.245240|1.167876|2.029374|1.621616|1.109659|9.267450|2.167445|2.368741|1.952001|1.402493|1.511824|1.708342|1.752388|0.048079|1.583854|1.996201|3.574561|2.997485|2.586761|2.772605|3.329299|3.787701|3.354388|2.790970|8.183607|6.834035|7.920529|13.788067|36.858105| |1.342906|1.261044|1.240721|1.159382|2.019120|1.622114|1.096493|9.227303|2.150655|2.379368|1.928198|1.371672|1.464823|1.650808|1.719310|0.047314|1.568890|1.963510|3.516559|2.960525|2.576595|2.779237|3.417755|3.987213|3.454589|2.802943|9.369981|7.909306|6.884467|7.977917|13.749744|36.858105| |1.465102|1.362844|1.335972|1.238778|2.155110|1.742052|1.163770|9.973236|2.306720|2.592826|2.087322|1.469373|1.565644|1.779851|1.885070|0.051925|1.717012|2.187372|3.911800|3.349877|3.003007|3.283795|4.252293|5.268196|4.306351|3.314517|14.474651|13.679475|7.955957|6.907816|7.941120|13.798147|36.858105| |1.450462|1.337398|1.301935|1.204650|2.103570|1.709750|1.127221|9.690332|2.237973|2.546353|1.998532|1.392602|1.463239|1.645630|1.766707|0.048881|1.639419|2.030781|3.630841|3.087411|2.722281|2.955992|3.731655|4.486712|3.784888|2.986710|11.714702|7.009148|4.762498|4.236938|4.770205|7.058930|10.957766|448.794386| |17.618892|8.941544|6.423275|4.653099|8.134955|8.266705|3.466883|39.755591|7.318523|12.727547|6.067689|3.468846|2.874067|2.911954|3.485550|0.091921|4.709685|3.255705|5.837059|3.890880|2.527060|2.464619|2.153656|1.966671|1.996998|2.236595|3.129259|1.588995|1.556928|1.405854|1.308837|1.327613|1.451876|11.618127|0.500000| |17.620385|9.018215|5.448220|4.458082|8.844457|10.417704|3.305762|29.857816|5.875114|8.089242|5.030056|3.116906|2.618913|2.698393|3.091013|0.078830|4.007560|3.010534|5.704317|3.552544|2.368178|2.397974|2.116641|1.901045|1.885400|2.075257|3.052493|1.560729|1.532360|1.390440|1.297398|1.314393|1.431614|11.440720|0.299059|0.500000| |17.586796|8.902320|6.270482|4.597018|8.138329|8.365399|3.423794|38.099437|6.841119|10.561927|6.918276|3.966281|3.296658|3.516289|4.299064|0.105839|6.181381|4.149904|7.876026|4.650971|2.974271|2.963588|2.511789|2.223673|2.226898|2.522802|3.482224|1.762718|1.739248|1.558545|1.436318|1.449364|1.590373|12.569622|0.302315|0.300886|0.500000| |3.367314|4.533691|5.864354|8.999409|12.352340|6.510325|17.557999|32.836885|8.838858|6.220308|5.767690|4.905227|3.653805|3.068205|2.900469|0.075220|3.446861|2.466240|4.396825|2.902384|1.864742|1.802616|1.596893|1.480224|1.512877|1.683734|2.386140|1.269781|1.297710|1.210874|1.120075|1.101896|1.165592|9.013095|0.085999|0.084993|0.089105|0.500000| |3.362582|4.538254|5.702563|9.035076|13.150159|6.703041|17.588101|31.289009|8.757777|6.240030|4.933706|3.786139|2.944024|2.547219|2.516516|0.066917|3.000286|2.178982|3.859285|2.622173|1.704918|1.647616|1.475253|1.378420|1.410500|1.558341|2.237838|1.187449|1.202990|1.123364|1.046761|1.036396|1.097460|8.569863|0.088771|0.085941|0.084921|0.302009|0.500000| |3.463138|4.590830|6.687522|8.943562|10.341290|5.987674|17.684357|43.081290|14.215841|7.653683|6.645043|5.297439|3.833746|3.113710|3.046652|0.081907|3.666604|2.516255|4.345112|3.005305|1.909389|1.810423|1.601103|1.499945|1.553531|1.742005|2.411268|1.276182|1.297957|1.206464|1.117048|1.102995|1.171066|9.095511|0.092980|0.084625|0.090466|0.299010|0.299653|0.500000| |3.838758|4.620819|5.895294|5.507897|7.871746|5.553629|5.158705|43.409023|9.594638|7.864125|12.318891|17.475648|8.823116|6.743503|5.682404|0.132879|6.949730|4.231355|7.367856|4.547001|2.726455|2.570306|2.168187|1.971376|2.036970|2.358675|3.077553|1.622593|1.678244|1.537824|1.392480|1.360129|1.453598|11.048781|0.096437|0.091431|0.115101|0.155293|0.110988|0.145981|0.500000| |3.370190|4.028031|5.531825|5.244729|7.034253|4.811788|5.557155|49.975257|14.054444|8.434543|12.478236|17.670744|8.868559|5.513220|4.908960|0.130571|5.649184|3.578750|5.888170|4.121165|2.480331|2.278162|1.955032|1.823499|1.920156|2.223120|2.866437|1.513879|1.560240|1.436470|1.308164|1.280396|1.365015|10.429508|0.089828|0.080123|0.096813|0.155049|0.118753|0.185507|0.300424|0.500000| |2.673619|2.949406|3.487733|3.329643|5.066007|3.650555|3.405960|28.503557|7.078171|5.843897|7.689279|8.898759|17.547699|8.830250|5.503337|0.140199|4.902428|4.096889|6.667790|4.706410|2.808679|2.558307|2.174217|2.022291|2.136374|2.497199|3.147087|1.685057|1.780117|1.643025|1.471192|1.416110|1.500255|11.201854|0.070478|0.065988|0.080186|0.101450|0.079697|0.101823|0.216375|0.211865|0.500000| |2.795537|3.008472|3.619130|3.271996|4.882768|3.591554|3.268663|33.441163|8.382701|7.001579|9.530009|8.918849|17.547482|8.832093|6.775771|0.201657|5.694357|4.512139|6.772004|5.378320|3.079666|2.682897|2.263379|2.139843|2.322027|2.782567|3.299854|1.744185|1.822229|1.664201|1.492761|1.448878|1.548719|11.649583|0.076111|0.067666|0.083934|0.091665|0.077143|0.101405|0.174070|0.219270|0.302326|0.500000| |3.136354|3.268176|3.569739|3.219345|5.150136|3.965076|2.992429|27.770410|6.071230|6.103571|7.856397|6.751290|8.824597|17.546886|8.875424|0.174248|6.826599|7.120852|12.282773|6.856741|3.893828|3.618020|2.893203|2.563578|2.652289|3.176829|3.870962|2.041696|2.162491|1.948459|1.717045|1.654668|1.778685|13.164560|0.080234|0.077405|0.100407|0.087474|0.071152|0.084514|0.196867|0.138673|0.214950|0.173345|0.500000| |2.648605|2.705934|2.985141|2.695440|4.281481|3.279908|2.579197|24.745661|5.665010|5.646523|6.743285|5.498033|8.824453|17.544290|8.793151|0.213757|5.498243|6.880438|9.905801|7.863052|4.292371|3.674315|2.961389|2.727352|2.947702|3.650018|4.074079|2.158542|2.313991|2.078742|1.813468|1.735688|1.864521|13.655726|0.070482|0.065668|0.082962|0.073866|0.062490|0.075080|0.138550|0.123704|0.210458|0.214860|0.302950|0.500000| |5.690230|5.117176|5.401544|3.983431|6.214301|5.268023|3.286233|49.968985|8.485092|14.270847|12.492893|5.649880|4.906410|5.510301|8.839626|0.217475|17.672189|6.917877|10.692253|7.245099|4.017053|3.606353|2.891776|2.603559|2.743009|3.329220|3.929756|1.975238|1.973324|1.744897|1.580855|1.581749|1.744867|13.546807|0.157097|0.122739|0.201298|0.086346|0.078921|0.093939|0.142867|0.127614|0.108011|0.128053|0.139983|0.123391|0.500000| |5.471207|5.478497|5.716478|4.450689|7.062361|5.907390|3.630868|42.992421|7.784031|9.674150|12.275666|6.957216|5.750108|6.837465|8.859207|0.174813|17.542794|7.099847|13.112070|6.558838|3.747608|3.565243|2.844850|2.492282|2.549363|3.028491|3.785082|1.937544|1.970456|1.757784|1.583126|1.565841|1.709507|13.081986|0.132272|0.123345|0.197834|0.100065|0.085023|0.099903|0.206037|0.142549|0.129175|0.132226|0.202172|0.139881|0.300494|0.500000| |2.766792|2.588009|2.703801|2.332474|3.791898|3.053151|2.141792|22.962108|5.020983|6.030499|5.560269|3.597207|4.166692|5.505007|7.665691|0.249994|5.146025|9.496922|10.891855|26.086804|9.345294|5.744234|4.293001|4.093101|4.934074|7.674865|5.646169|2.789373|2.852854|2.416479|2.105188|2.079333|2.336480|17.391533|0.077040|0.068627|0.088529|0.058704|0.053400|0.062001|0.090856|0.086287|0.097789|0.118784|0.129244|0.162275|0.143591|0.122318|0.500000| |2.784292|2.503977|2.411231|2.134805|3.680542|3.070917|1.914613|18.014150|3.878264|4.664430|4.078743|2.764424|2.939659|3.804367|4.431799|0.108704|3.861437|6.838413|15.142177|9.512417|8.910499|17.833115|8.932262|5.654342|4.950815|5.649609|7.506010|3.587973|3.613307|2.934085|2.522687|2.514407|2.901185|21.252457|0.073475|0.073206|0.091826|0.053479|0.048469|0.052988|0.077479|0.066558|0.074505|0.076247|0.110945|0.105059|0.107449|0.112227|0.143170|0.500000| |2.136980|1.934207|1.857305|1.684099|2.940146|2.432972|1.538152|13.734859|3.053988|3.583635|2.961540|2.043171|2.161049|2.604802|2.875202|0.075294|2.599579|3.730788|7.214023|5.634917|5.644782|8.915875|17.731389|8.970337|5.666688|4.975412|13.007438|5.764876|5.263578|3.947019|3.398364|3.524620|4.364745|30.996434|0.057521|0.057765|0.067254|0.042885|0.039680|0.042578|0.057003|0.051002|0.056300|0.057576|0.074445|0.073978|0.073563|0.073999|0.098042|0.215122|0.500000| |1.825699|1.687844|1.689352|1.527565|2.591702|2.093527|1.428213|13.221580|3.030724|3.501288|2.837048|1.944703|2.124559|2.476312|2.757865|0.079548|2.379615|3.273667|5.371546|5.726311|5.623073|4.943227|5.662574|8.943598|17.734477|8.903980|12.976553|5.831096|5.252977|3.966408|3.442600|3.592800|4.462753|31.804180|0.051115|0.048059|0.055902|0.039341|0.036917|0.040593|0.051820|0.049625|0.054840|0.059874|0.065608|0.073537|0.068174|0.062994|0.116573|0.107512|0.124691|0.500000| |2.179888|2.025799|2.072337|1.838522|3.054089|2.457425|1.712940|16.894237|3.830289|4.486146|3.769439|2.533085|2.849739|3.434269|4.035809|0.123034|3.231164|4.831594|7.098934|10.016070|8.890836|5.640557|4.972572|5.671504|8.964304|17.696148|7.520173|3.611589|3.617519|2.946611|2.543941|2.542195|2.934192|21.537666|0.061297|0.055854|0.067732|0.047001|0.043644|0.049278|0.065716|0.063564|0.071209|0.081888|0.086617|0.103875|0.092423|0.081905|0.235715|0.124038|0.107878|0.215560|0.500000| |1.692627|1.593552|1.585366|1.463348|2.515044|2.018753|1.377239|11.991148|2.758348|3.062685|2.611896|1.865316|2.060477|2.445400|2.537653|0.068989|2.189181|3.067279|5.441159|4.849386|4.591517|5.020915|6.342241|7.478749|6.245643|4.988813|12.620763|8.933613|17.767570|8.920865|5.645469|4.961886|5.655866|31.532671|0.046036|0.045174|0.051968|0.038662|0.035581|0.038649|0.051179|0.047289|0.054899|0.056154|0.068065|0.073744|0.060198|0.060508|0.091427|0.116986|0.159644|0.155990|0.115816|0.500000| |1.405754|1.343560|1.341018|1.259408|2.176000|1.728038|1.201596|10.025452|2.347394|2.531956|2.149552|1.564827|1.719121|1.968781|1.976542|0.053895|1.747645|2.261907|4.040777|3.395588|2.914223|3.091030|3.569661|3.910473|3.570372|3.096260|7.459139|5.652916|8.955413|17.721770|8.921674|5.659417|4.970459|27.450454|0.038201|0.037831|0.042430|0.033904|0.031295|0.033664|0.043186|0.040313|0.046803|0.046960|0.055163|0.059188|0.047705|0.048573|0.065944|0.078238|0.098313|0.098280|0.078330|0.216339|0.500000| |1.243877|1.184068|1.173575|1.106546|1.925067|1.532337|1.056128|8.707271|2.047407|2.216243|1.827479|1.320761|1.422170|1.592702|1.618991|0.044427|1.470532|1.820511|3.261686|2.702017|2.282883|2.424229|2.825519|3.130379|2.844760|2.439158|6.497419|4.932971|5.633648|8.900734|17.733121|8.921159|5.651736|31.635708|0.033996|0.033775|0.037150|0.029662|0.027739|0.029522|0.036481|0.034372|0.038668|0.039023|0.044531|0.046940|0.040641|0.040880|0.053006|0.062226|0.080246|0.081200|0.062737|0.124063|0.214072|0.500000| 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