Version2.4 2021-06-06T23:48:24Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 04-Nov-2019 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE COc1ccc(c(c1)OC)C(=O)C2=C(C(=O)N([C@H]2c3ccc(cc3F)F)c4cccc(c4)C(=O)[O-])[O-] C13213122 RHF 6-31G(d) (6D,7F) COc1ccc(c(c1)OC)C(=O)C2=C(C(=O)N([C@H]2c3ccc(cc3F)F)c4cccc(c4)C(=O)[O-])[O-] C01[X(C26H17F2N1O7)] 153 C1 574 COc1ccc(c(c1)OC)C(=O)C1=C([O-])C(=O)N([C@H]1c1ccc(cc1F)F)c1cccc(c1)C(=O)[O-] COc1ccc(c(c1)OC)C(=O)C1=C([O-])C(=O)N([C@H]1c1ccc(cc1F)F)c1cccc(c1)C(=O)[O-] COc1ccc(c(OC)c1)C(=O)C2=C([O-])C(=O)N([C@H]2c3ccc(F)cc3F)c4cccc(c4)C([O-])=O InChIKey=OLYPMVDDRGRSLV-QFIPXVFZSA-L InChI=1S/C26H19F2NO7/c1-35-16-7-9-18(20(12-16)36-2)23(30)21-22(17-8-6-14(27)11-19(17)28)29(25(32)24(21)31)15-5-3-4-13(10-15)26(33)34/h3-12,22,31H,1-2H3,(H,33,34)/p-2/t22-/m0/s1 InChI=1/C26H19F2NO7/c1-35-16-7-9-18(20(12-16)36-2)23(30)21-22(17-8-6-14(27)11-19(17)28)29(25(32)24(21)31)15-5-3-4-13(10-15)26(33)34/h3-12,22,31H,1-2H3,(H,33,34)/p-2/t22-/m0/s1/fC26H17F2NO7/h31h/q-2 COc1ccc(c(c1)OC)C(=O)C2=C(C(=O)N([C@H]2c3ccc(cc3F)F)c4cccc(c4)C(=O)[O-])[O-] C01[X(C26H17F2N1O7)] 153 C01 574 COc1ccc(c(c1)OC)C(=O)C1=C([O-])C(=O)N([C@H]1c1ccc(cc1F)F)c1cccc(c1)C(=O)[O-] CO[C]1[CH][CH][C]([C]([CH]1)OC)[C]([C]1[C](=O)C(=O)N([C@H]1[C]1[CH][CH][C]([CH][C]1F)F)[C]1[CH][CH][CH][C]([CH]1)[C]([O])=O)=O CO[C]1[CH][CH][C]([C]([CH]1)OC)C(=O)[C]2[C@H]([C]3[CH][CH][C](F)[CH][C]3F)N([C]4[CH][CH][CH][C]([CH]4)C([O])=O)C(=O)C2=O InChIKey=QLYCVACWOUUNFI-QFIPXVFZSA-N InChI=1S/C26H17F2NO7/c1-35-16-7-9-18(20(12-16)36-2)23(30)21-22(17-8-6-14(27)11-19(17)28)29(25(32)24(21)31)15-5-3-4-13(10-15)26(33)34/h3-12,22H,1-2H3/t22-/m0/s1 InChI=1/C26H17F2NO7/c1-35-16-7-9-18(20(12-16)36-2)23(30)21-22(17-8-6-14(27)11-19(17)28)29(25(32)24(21)31)15-5-3-4-13(10-15)26(33)34/h3-12,22H,1-2H3/t22-/m0/s1 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40 41 42 43 44 45 46 47 48 49 50 51 52 53 6 8 6 6 6 6 6 6 8 6 6 8 6 6 6 8 7 6 1 6 6 6 6 6 6 9 9 6 6 6 6 6 6 6 8 8 8 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 12.00000 15.99491 12.00000 12.00000 12.00000 15.99491 14.00307 12.00000 1.00783 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 18.99840 18.99840 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 15.99491 15.99491 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 11609.5394 22952.8720 25311.4534 0.99990 0.01396 -0.00253 -0.01399 0.99984 -0.01132 0.00238 0.01135 0.99993 1 0.00746 0.00377 0.00342 0.15545 0.07863 0.07130 15.16 21.57 33.92 43.11 43.83 61.58 63.77 78.15 99.22 102.94 122.16 125.69 134.49 177.71 195.94 218.91 243.28 259.04 285.38 285.83 319.72 332.19 368.93 379.25 388.31 399.75 433.96 442.11 445.21 450.60 477.73 536.91 556.13 575.08 583.88 640.22 666.74 686.52 708.20 729.96 763.13 777.45 790.71 803.47 814.15 818.40 866.08 874.25 903.96 922.73 942.92 987.27 1004.89 1026.99 1072.69 1078.89 1121.65 1137.42 1143.19 1170.40 1195.50 1218.38 1226.15 1249.86 1266.07 1291.17 1307.54 1308.37 1321.31 1331.34 1343.16 1354.49 1359.01 1444.32 1477.52 1493.70 1529.70 1540.62 1542.95 1563.24 1569.80 1586.06 1622.04 1699.99 1700.87 1715.47 1721.32 1734.07 1766.20 1775.06 1777.76 1804.63 1825.89 1854.80 1863.64 1864.44 1867.24 1871.66 1877.31 1890.80 1926.10 1932.11 1958.60 1984.21 1985.46 1993.92 2037.27 2040.83 2046.84 2094.20 2178.50 2194.86 2215.21 2252.20 2273.90 2281.15 2291.67 2340.06 2363.83 2372.56 2374.15 2374.33 2388.42 2397.06 2418.40 2419.23 2556.16 2562.01 2579.82 2584.54 2593.47 2609.76 2623.45 2742.66 2792.80 2846.23 4592.94 4599.56 4663.23 4683.79 4685.17 4740.20 4770.57 4772.69 4825.86 4841.34 4873.88 4887.25 4896.67 4900.42 4906.17 4909.14 4919.27 0.411054 0.440558 0.441502 0.345450 -1771.402784 -1771.373280 -1771.372336 -1771.468388 3.221600D-04 MUNgauss RevisionA2.1 retrievium 06-Jun-2021 DUDE COc1ccc(c(c1)OC)C(=O)C2=C(C(=O)N([C@H]2c3ccc(cc3F)F)c4cccc(c4)C(=O)[O-])[O-] C13213122 RHF 6-31G(d) (6D,10F) C1 493.097309 |X|Y|Z| 99.400919 61.396837 51.911472 68.171039 24 6 7 23 1 |36.858105| |13.683120|73.516695| |8.038269|24.879803|36.858105| |6.761738|13.976803|13.854942|36.858105| |4.523323|9.239923|8.000428|13.623471|36.858105| |3.780834|8.147417|6.805572|7.821223|13.874238|36.858105| |3.993723|9.398316|7.920643|6.845467|8.024359|13.558929|36.858105| |5.278138|14.569540|13.654696|7.925808|6.942715|7.866045|13.797850|36.858105| |3.184932|7.174677|5.210425|4.615784|5.322760|8.157398|14.159611|7.951288|73.516695| |3.017770|6.837188|4.542222|3.807384|4.019909|5.258553|8.031645|6.797702|24.335219|36.858105| |2.913818|5.957792|4.402515|4.973331|7.553229|12.442259|7.419379|4.968814|12.038568|4.541428|36.858105| |2.663012|5.420228|3.863354|4.215635|5.784192|8.180628|6.169299|4.383123|10.984833|4.324711|15.684807|73.516695| |2.623131|5.193835|3.677605|4.188137|5.921286|7.552624|5.328458|3.981199|9.038109|3.788532|13.394014|14.333257|36.858105| |2.211257|4.280541|2.901865|3.252023|4.244711|4.933488|3.881407|3.089974|6.905256|3.099068|7.563547|11.365043|13.460546|36.858105| |2.079273|3.949264|2.614571|2.921591|3.630681|3.951978|3.254947|2.721912|5.720118|2.694185|5.081870|7.626759|8.061818|12.352074|36.858105| |1.852723|3.476175|2.252238|2.492541|2.991233|3.179460|2.705641|2.324616|4.792423|2.323973|3.920537|6.241852|5.416705|7.778189|15.906624|73.516695| |2.294921|4.364921|2.909861|3.262419|4.035991|4.327431|3.568557|3.009129|6.112734|2.883219|5.118895|7.210636|8.135904|8.137196|14.007311|14.831403|53.358707| |2.732409|5.336415|3.725677|4.242024|5.616886|6.341670|4.878962|3.913437|7.992746|3.565193|7.296511|9.032435|12.516861|7.919714|8.070966|9.640289|17.701081|36.858105| |3.044816|5.829276|4.105787|4.955891|6.607637|6.450043|4.812132|4.062074|7.350828|3.328707|6.416597|8.166087|8.715693|6.059878|6.250151|8.230309|12.499849|17.590490|0.500000| |2.782081|5.580043|3.839528|4.026541|4.869268|5.787784|5.235121|4.255421|9.039318|4.198136|5.825934|7.731274|7.403225|5.383949|5.467815|7.421145|10.533527|12.442454|0.249834|36.858105| |2.435366|4.923998|3.292192|3.307246|3.882506|4.794741|4.718934|3.808056|9.267871|4.517617|5.164346|7.416486|6.190528|5.052728|4.981519|7.064989|8.295687|7.476098|0.155749|13.681962|36.858105| |2.342157|4.758691|3.071238|2.955910|3.277750|3.919719|4.186489|3.598395|8.475643|4.654348|3.953673|6.027266|4.322909|3.716013|3.699312|5.602008|5.898139|4.968828|0.116342|7.833826|13.783046|36.858105| |2.542341|5.168954|3.261375|3.063752|3.248042|3.717417|4.083148|3.762698|7.760806|4.457322|3.489617|5.316127|3.704362|3.144949|3.176866|4.884641|5.176380|4.417312|0.111446|6.848623|8.038958|13.812440|36.858105| |2.945323|5.949033|3.785725|3.593570|3.737900|4.098846|4.389662|4.191256|7.610998|4.159969|3.645261|5.394055|3.884407|3.193260|3.264446|4.960864|5.551493|4.953017|0.132949|7.819846|6.897148|7.914281|13.886476|36.858105| |3.112265|6.232008|4.190379|4.252266|4.696580|5.124152|5.003496|4.506715|8.182091|4.065963|4.540361|6.339789|5.098984|3.950257|4.071009|5.923012|7.451330|7.458541|0.203718|13.808279|8.096297|6.944642|8.087117|13.762155|36.858105| |3.548113|6.830553|4.561602|4.889824|5.150610|4.967491|4.618982|4.446701|7.026226|3.484268|4.191943|5.903661|4.606127|3.618780|3.767959|5.581384|6.837544|6.631884|0.222617|8.112375|5.314004|4.674385|5.361159|8.246242|14.291370|97.533100| |2.345769|4.732426|2.869725|2.644619|2.721367|3.046281|3.406433|3.281277|6.534126|4.011744|2.857601|4.513373|2.958154|2.596409|2.617465|4.144943|4.110152|3.371329|0.087308|4.624265|5.303302|8.128887|14.237180|8.169574|5.323046|9.234239|97.533100| |2.183168|4.062975|2.629651|2.923411|3.411572|3.476676|2.996937|2.655330|5.090912|2.501318|3.786582|5.579831|5.135801|5.119090|7.749149|11.782923|18.134129|7.546606|0.195401|6.072857|4.895123|3.863739|3.597559|3.960849|5.114670|11.242963|6.584447|36.858105| |2.211571|4.012129|2.566114|2.921169|3.339604|3.215961|2.748811|2.503713|4.546410|2.246153|3.387561|5.078215|4.325004|4.276863|5.837624|9.593367|10.680877|5.832077|0.176814|4.648089|3.745039|3.111049|3.017396|3.406959|4.296975|10.474018|5.700624|13.714786|36.858105| |2.048932|3.661501|2.279750|2.544608|2.788629|2.668139|2.360699|2.208651|3.930267|1.992088|2.738307|4.217733|3.308462|3.278411|4.200193|7.331466|7.010699|4.208664|0.126312|3.722564|3.136780|2.745941|2.736762|3.082026|3.664482|9.039044|5.325784|7.938203|13.766122|36.858105| |1.899146|3.419648|2.104763|2.285085|2.470763|2.422724|2.205261|2.072368|3.743799|1.933221|2.482293|3.862447|2.964218|2.948613|3.741577|6.635365|6.172762|3.733324|0.106829|3.558479|3.122720|2.819805|2.830994|3.129778|3.559579|8.402217|5.584320|6.874562|7.936540|13.742428|36.858105| |1.878271|3.445432|2.135311|2.281255|2.493208|2.522027|2.322193|2.151742|4.022270|2.085139|2.619871|4.060170|3.179313|3.175660|4.108784|7.218883|6.941879|4.067840|0.110084|4.073464|3.690092|3.336457|3.286966|3.534757|3.971382|8.755987|6.399272|7.872742|6.823642|7.895854|13.721899|36.858105| |2.003564|3.737303|2.368791|2.545730|2.870673|2.976242|2.693409|2.425303|4.697923|2.384802|3.179440|4.820735|4.063777|4.072242|5.635091|9.396042|10.550670|5.505829|0.139647|5.415408|4.829633|4.069438|3.813361|4.057184|4.831194|10.070598|7.083296|13.731597|7.937897|6.891877|7.969256|13.679817|36.858105| |1.700654|3.125191|1.905599|1.990673|2.136621|2.184414|2.068557|1.938751|3.645586|1.936813|2.252879|3.562524|2.644696|2.647192|3.251226|5.797340|5.164024|3.221396|0.086161|3.395205|3.271171|3.143632|3.135338|3.239401|3.386894|7.276655|6.375467|4.953814|4.389197|4.973158|7.479595|12.302337|7.428868|36.858105| |1.609831|2.924624|1.760808|1.837860|1.944126|1.960382|1.864061|1.772226|3.263358|1.746047|1.999565|3.193358|2.300659|2.298990|2.757671|4.960411|4.278913|2.743611|0.075094|2.851805|2.727109|2.653790|2.697806|2.815993|2.906774|6.441466|5.624532|3.990444|3.821941|4.582896|6.875524|8.091456|5.255240|15.424699|73.516695| |1.664591|3.096380|1.892076|1.951695|2.103154|2.194868|2.105853|1.958245|3.783173|2.027960|2.282578|3.627248|2.672437|2.683283|3.247980|5.756851|5.077949|3.205679|0.083231|3.501666|3.555301|3.509863|3.423799|3.374334|3.427453|7.037047|7.020134|4.546804|3.808854|3.994649|5.273170|8.082132|6.796417|15.476800|15.190030|73.516695| |2.017251|3.888475|2.592289|2.865946|3.627883|4.164109|3.409888|2.762624|6.205684|2.846433|6.179371|11.040242|7.889885|15.745331|7.960095|11.825632|7.474581|5.286798|0.123058|4.082630|4.041816|3.170990|2.703322|2.696035|3.188836|6.651607|5.175764|3.979079|3.483927|2.799605|2.550776|2.719685|3.343502|2.334866|3.659843|4.227628|73.516695| |17.606590|17.009533|5.874368|4.915732|3.620906|3.172505|3.413262|4.419815|5.051756|2.780926|2.532398|4.174766|2.304794|1.977041|1.872846|2.997277|2.796665|2.399480|0.073047|2.475274|2.211844|2.166421|2.367296|2.702728|2.772093|6.971368|5.025395|1.973889|1.995188|1.874324|1.758211|1.741329|1.838772|1.597542|2.705935|2.786357|3.234572|0.500000| |17.536390|16.451093|6.999630|6.752994|4.560953|3.703643|3.764364|4.726243|5.356757|2.802783|2.899225|4.785628|2.585516|2.199920|2.051504|3.263172|3.037198|2.634775|0.081681|2.603867|2.287360|2.170593|2.306758|2.629712|2.826432|7.198217|4.774432|2.110356|2.157459|1.991406|1.828420|1.796784|1.918335|1.620348|2.731637|2.812804|3.602304|0.299982|0.500000| |17.552753|16.468072|7.126347|6.795955|4.615953|3.763604|3.838267|4.832708|5.457102|2.877632|2.923933|4.652374|2.706319|2.276371|2.178885|3.446420|3.327785|2.908625|0.092121|2.956691|2.530604|2.420780|2.658412|3.166519|3.392018|9.122287|5.467360|2.362277|2.423507|2.257055|2.079649|2.037437|2.160126|1.830317|3.086250|3.156424|3.648146|0.299682|0.299458|0.500000| |7.448816|12.418990|8.873526|17.758445|8.894725|5.616386|4.941431|5.620681|6.514287|3.143691|4.085808|6.336665|3.625090|2.938142|2.709632|4.185813|4.097336|3.739322|0.123560|3.485690|2.883559|2.602395|2.714134|3.185181|3.718253|9.963005|5.358430|2.778031|2.866822|2.539444|2.256885|2.208346|2.418126|1.925093|3.195638|3.317590|4.655364|0.145710|0.226745|0.222393|0.500000| |3.916193|7.448584|5.685065|8.924755|17.710028|9.037628|5.688230|4.987526|7.628871|3.351536|7.088757|9.842253|6.163790|4.584679|3.952281|5.787258|5.887395|5.790928|0.199446|4.548390|3.612867|3.007297|2.942482|3.360938|4.262507|10.744293|5.576866|3.645697|3.688870|3.017777|2.600394|2.578297|2.968483|2.173090|3.523506|3.759338|6.929596|0.089039|0.112812|0.113633|0.216505|0.500000| |4.919403|13.627286|8.993392|5.676694|4.993285|5.593275|8.852798|17.773708|12.574759|7.514575|4.039585|6.592910|3.363472|2.711826|2.425622|3.742172|3.621681|3.333800|0.094359|3.730748|3.497131|3.475130|3.709284|4.002239|4.015660|8.718366|7.590045|2.389682|2.247143|2.016775|1.921457|2.004889|2.233351|1.838964|3.002761|3.325213|4.379612|0.122125|0.119550|0.122263|0.124373|0.108199|0.500000| |2.577983|5.613423|3.634603|3.193772|3.436397|4.423242|5.896045|4.941000|17.061686|17.633535|4.191710|7.317761|3.619151|3.070921|2.670542|4.134601|3.818850|3.360004|0.085082|3.949894|4.543424|4.815179|4.346354|3.827093|3.697560|7.020461|9.001313|2.429298|2.156627|1.918247|1.879197|2.048018|2.348521|1.923015|3.071116|3.623733|5.098980|0.066753|0.067300|0.068959|0.075252|0.082557|0.146625|0.500000| |3.105411|7.136559|4.564145|3.708240|3.761970|4.671315|6.937194|6.750905|16.453307|17.524568|3.978257|7.005285|3.282221|2.744663|2.392714|3.721913|3.443217|3.067166|0.081515|3.459185|3.605997|3.689278|3.630453|3.488290|3.417600|6.898778|7.629766|2.225868|2.038027|1.825039|1.765130|1.879972|2.117494|1.753306|2.841163|3.240226|4.570064|0.080475|0.080600|0.080046|0.085931|0.087344|0.229328|0.299971|0.500000| |3.157520|7.192496|4.653161|3.810045|3.888984|4.844313|7.132789|6.825460|16.477596|17.558425|4.072330|6.617059|3.579890|2.926261|2.632843|4.045994|3.937801|3.576489|0.093918|4.438413|4.725288|5.194113|5.391503|5.012593|4.585654|8.671489|11.051733|2.564988|2.300917|2.059214|2.016013|2.182859|2.479894|2.039602|3.268045|3.801485|4.700143|0.081421|0.079345|0.084776|0.088053|0.090146|0.222138|0.299945|0.298814|0.500000| |2.234700|4.483419|2.988410|3.044827|3.642838|4.548362|4.334489|3.437572|8.785495|4.202371|5.428794|8.062347|6.788566|6.024844|5.691232|7.993290|8.537291|7.017960|0.141601|8.985392|17.745762|8.954337|5.694483|4.966840|5.730036|9.614689|9.599590|4.731676|3.603526|2.990972|2.956768|3.480793|4.588359|3.093480|4.597298|6.010509|8.595725|0.056523|0.059213|0.063883|0.074322|0.096386|0.087733|0.122042|0.094825|0.115527|0.500000| |2.109375|4.263424|2.703635|2.588642|2.846200|3.383715|3.641973|3.165844|7.623410|4.379668|3.496868|5.562398|3.751014|3.382449|3.339651|5.209051|5.054265|4.054428|0.096105|5.588583|8.856567|17.741263|8.944841|5.649218|4.991150|8.324756|16.617127|3.340773|2.732586|2.449820|2.538267|2.997688|3.569560|2.915552|4.415431|5.906257|5.318599|0.054794|0.054693|0.059928|0.063934|0.073195|0.086766|0.134001|0.097993|0.131792|0.213610|0.500000| |3.074534|6.109224|3.718193|3.467317|3.434776|3.603797|3.893023|3.963926|6.583429|3.706862|3.144212|4.755312|3.278390|2.751810|2.820897|4.380845|4.694772|4.056564|0.114049|5.602316|4.968162|5.630103|8.902789|17.762260|8.893410|16.858631|16.536003|3.465503|3.119156|2.917519|2.978237|3.269611|3.564374|3.057088|4.860508|5.558255|4.209530|0.079544|0.074853|0.093121|0.087303|0.086043|0.107799|0.093848|0.089720|0.124935|0.107821|0.124160|0.500000| |2.320732|4.178974|2.698167|3.165522|3.685257|3.436205|2.848847|2.589066|4.624336|2.251854|3.631884|5.433330|4.603668|4.531361|5.866645|9.448769|9.873974|5.894251|0.191373|4.374396|3.497374|2.888997|2.796342|3.162510|4.014350|10.060149|5.309423|8.927907|17.692943|8.881259|5.634201|4.924519|5.649496|3.516797|5.607318|5.593448|6.574055|0.057591|0.063741|0.070615|0.087361|0.118179|0.063745|0.059608|0.057210|0.063375|0.094675|0.070812|0.080899|0.500000| |2.018303|3.548701|2.185048|2.454611|2.645631|2.479378|2.197221|2.084494|3.628733|1.846833|2.514105|3.923459|2.951706|2.921250|3.583281|6.320247|5.685817|3.602955|0.110471|3.186867|2.711620|2.409301|2.423419|2.730251|3.189718|8.048723|4.794038|5.643251|8.925350|17.664302|8.892353|5.621713|4.957628|4.062949|7.054364|5.922301|4.533010|0.051416|0.054895|0.061988|0.069373|0.080253|0.052963|0.049218|0.047510|0.052884|0.072136|0.060262|0.073166|0.214299|0.500000| |1.781265|3.180588|1.928962|2.075715|2.205111|2.152531|1.986018|1.891421|3.378930|1.766731|2.184206|3.446442|2.542971|2.530120|3.100211|5.561867|4.916592|3.098952|0.088968|3.011413|2.700295|2.504644|2.547727|2.795136|3.072918|7.286588|5.152087|4.955448|5.633784|8.859098|17.747406|9.011368|5.680852|7.067444|14.033746|8.673136|3.973176|0.046223|0.047643|0.054150|0.057419|0.064099|0.049160|0.047766|0.045168|0.051273|0.071150|0.063499|0.075540|0.123589|0.212674|0.500000| |1.941675|3.671135|2.327525|2.453526|2.769415|2.961323|2.736250|2.437520|4.907634|2.514780|3.204404|4.897999|4.071491|4.106484|5.480107|9.071144|9.621221|5.307341|0.127074|5.688319|5.622205|4.773799|4.258562|4.264799|4.872640|9.440911|7.845125|8.894754|5.641962|4.965451|5.675961|8.968552|17.762864|6.968638|8.590004|13.686711|6.047640|0.049731|0.051467|0.057532|0.063882|0.078025|0.062942|0.069874|0.061352|0.072705|0.150327|0.117595|0.101330|0.124128|0.107665|0.125196|0.500000| 1769.423964 -12038.937209 4813.020927 -226.445893 -5682.938211 3911.124337 -1771.813874 2.001351 408B00000000001E 45998FFCADEBA5BB 4519C383B5565260 4200385D80000004 B495C72F9A2489FE 43C19F3F01BDD346