Version2.0 2020-02-16T15:20:10Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 23-Dec-2019 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE C[C@H](C(=O)Nc1ccc(cc1)NC(=O)C)S[C@H]2NN=C(N2c3ccccc3)C4=c5ccccc5=[NH+]C4 C39933412 RHF 6-31G(d) (6D,7F) C[C@H](C(=O)Nc1ccc(cc1)NC(=O)C)S[C@H]2NN=C(N2c3ccccc3)C4=c5ccccc5=[NH+]C4 C01[X(C27H27N6O2S1)] 183 C1 598 CC(=O)Nc1ccc(cc1)NC(=O)[C@H](S[C@H]1NN=C(N1c1ccccc1)C1=c2ccccc2=[NH+]C1)C CC(=O)Nc1ccc(cc1)NC(=O)[C@H](S[C@H]1NN=C(N1c1ccccc1)C1=c2ccccc2=[NH+]C1)C C[C@@H](S[C@H]1NN=C(N1c2ccccc2)C3=C4C=CC=CC4=[NH+]C3)C(=O)Nc5ccc(NC(C)=O)cc5 InChIKey=FLGCGIJOYHNCIF-CRYYWNKWSA-O InChI=1S/C27H26N6O2S/c1-17(26(35)30-20-14-12-19(13-15-20)29-18(2)34)36-27-32-31-25(33(27)21-8-4-3-5-9-21)23-16-28-24-11-7-6-10-22(23)24/h3-15,17,27,32H,16H2,1-2H3,(H,29,34)(H,30,35)/p+1/t17-,27+/m1/s1 InChI=1/C27H26N6O2S/c1-17(26(35)30-20-14-12-19(13-15-20)29-18(2)34)36-27-32-31-25(33(27)21-8-4-3-5-9-21)23-16-28-24-11-7-6-10-22(23)24/h3-15,17,27,32H,16H2,1-2H3,(H,29,34)(H,30,35)/p+1/t17-,27+/m1/s1/fC27H27N6O2S/h28-30H/q+1 C[C@H](C(=O)Nc1ccc(cc1)NC(=O)C)S[C@H]2NN=C(N2c3ccccc3)C4=c5ccccc5=[NH+]C4 C01[X(C27H27N6O2S1)] 183 C01 598 CC(=O)Nc1ccc(cc1)NC(=O)[C@H](S[C@H]1NN=C(N1c1ccccc1)C1=c2ccccc2=[NH+]C1)C CC(=O)Nc1ccc(cc1)NC(=O)[C@H](S[C@H]1NN=C(N1c1ccccc1)C1=C2C=CC=C[C@H]2NC1)C C[C@@H](S[C@H]1NN=C(N1c2ccccc2)C3=C4C=CC=C[C@H]4NC3)C(=O)Nc5ccc(NC(C)=O)cc5 InChIKey=RBYJWQSCPXGEFI-ZVNQEMBASA-N InChI=1S/C27H28N6O2S/c1-17(26(35)30-20-14-12-19(13-15-20)29-18(2)34)36-27-32-31-25(33(27)21-8-4-3-5-9-21)23-16-28-24-11-7-6-10-22(23)24/h3-15,17,24,27-28,32H,16H2,1-2H3,(H,29,34)(H,30,35)/t17-,24-,27+/m1/s1 InChI=1/C27H28N6O2S/c1-17(26(35)30-20-14-12-19(13-15-20)29-18(2)34)36-27-32-31-25(33(27)21-8-4-3-5-9-21)23-16-28-24-11-7-6-10-22(23)24/h3-15,17,24,27-28,32H,16H2,1-2H3,(H,29,34)(H,30,35)/t17-,24-,27+/m1/s1/f/h29-30H 3794.8715684433 -1911.8750633 1-A 26996.8215 131 467 598 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -92.03539 -20.59505 -20.57713 -15.78018 -15.74731 -15.73134 -15.71899 -15.66268 -15.64960 -11.48719 -11.46375 -11.45264 -11.44853 -11.44485 -11.42195 -11.42193 -11.41151 -11.40259 -11.39983 -11.38953 -11.38843 -11.38171 -11.35642 -11.35104 -11.34481 -11.34426 -11.34160 -11.34032 -11.33522 -11.33175 -11.29777 -11.29578 -11.29133 -11.28289 -11.27911 -11.27619 -9.04598 -6.72872 -6.72707 -6.72524 -1.52930 -1.48566 -1.46601 -1.44600 -1.36598 -1.31942 -1.30993 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8.6193 2.3351 15.1697 1.2421 2.6705 0.5760 0.8450 3.7119 2.3688 85.3311 239.6916 33.2388 72.0667 3.2955 1.2973 0.9448 7.2612 3.0417 1.0388 0.6644 1.1432 3.4405 6.3498 7.7241 0.7177 0.8425 1.4234 2.0003 6.8788 3.0349 1.6566 2.3937 13.2625 1.2767 0.8745 2.2873 3.9582 1.0254 6.2347 1.8127 2.0643 1.1178 0.2834 1.3979 19.2858 4.7391 4.5649 18.2889 1.9217 32.5352 1.0800 0.2963 41.0205 102.5655 3.3663 1.1119 6.4274 4.0818 2.2501 4.0705 12.5227 5.3038 14.6799 7.3390 89.5302 31.6090 120.4810 117.5915 30.2014 21.9884 19.9198 39.1970 87.7499 28.1216 3.8639 10.7627 39.2612 6.1687 58.5515 8.9766 3.1426 29.8430 52.3927 3.3776 21.7477 22.9217 3.0289 2.3724 4.3940 61.8192 61.4250 8.5634 21.9295 9.6011 3.1530 4.3445 25.1958 7.6802 9.7195 27.6470 6.2581 6.8132 1.6124 4.9099 125.9369 12.2302 4.8822 0.8629 30.4785 3.1756 1.5905 75.0761 0.3839 40.3593 7.4733 5.7728 52.8751 8.3814 170.9422 5.8248 9.3162 99.8024 15.3206 3.3501 11.8985 17.5456 21.9599 1.7528 24.0034 10.1126 45.5034 31.2635 111.3825 66.4138 199.9567 1.4976 1.2570 59.2569 3.8266 15.4941 59.1507 129.6414 1.9902 6.5386 13.8331 398.1020 16.9877 76.6527 81.4549 12.9788 31.6608 19.0557 19.6710 1679.3031 57.7959 9.4093 2.6887 0.5506 937.9146 38.7305 161.4569 21.5139 1.8450 58.8233 1299.4789 623.4315 326.3382 18.5747 21.1986 74.8292 120.5097 121.5503 119.6359 65.1188 59.5147 79.5297 85.9940 46.7168 90.6904 57.8370 27.0435 110.3478 61.9180 100.8625 79.3638 140.0664 132.9362 178.5199 274.0477 40.4978 42.8764 66.9693 292.1822 103.5846 64.3425 142.0313 0.7463 0.7477 0.7481 0.7059 0.7088 0.7149 0.6804 0.5594 0.6474 0.7402 0.7500 0.7494 0.6377 0.6185 0.7184 0.4228 0.7396 0.4963 0.6883 0.3844 0.4686 0.6703 0.7137 0.6346 0.7081 0.3492 0.1946 0.5457 0.0424 0.4834 0.4805 0.5779 0.2520 0.4380 0.3461 0.6114 0.4402 0.4314 0.7359 0.3071 0.3020 0.7399 0.7234 0.4404 0.2297 0.4669 0.4367 0.1122 0.2508 0.7499 0.5715 0.5120 0.3784 0.3638 0.3163 0.7497 0.5698 0.4827 0.2617 0.3730 0.4337 0.6738 0.3565 0.1356 0.5964 0.5024 0.7023 0.4175 0.4831 0.2799 0.4621 0.0868 0.4283 0.5506 0.7500 0.5767 0.4621 0.5073 0.2642 0.5115 0.7335 0.6046 0.6898 0.7471 0.3316 0.2728 0.0898 0.1862 0.4416 0.5672 0.7178 0.3767 0.1196 0.6938 0.3590 0.3447 0.7362 0.6257 0.2568 0.1290 0.1533 0.3289 0.3559 0.3659 0.4822 0.4068 0.2643 0.1570 0.1689 0.3643 0.7441 0.6844 0.1597 0.7293 0.4247 0.2569 0.6617 0.1891 0.1711 0.3868 0.1392 0.2650 0.4764 0.5477 0.5533 0.5710 0.3084 0.2940 0.2566 0.7500 0.5319 0.3632 0.2172 0.2599 0.2675 0.7111 0.7483 0.2699 0.7456 0.6709 0.3137 0.3882 0.2510 0.4913 0.6039 0.3532 0.2130 0.3029 0.4261 0.6337 0.6837 0.3885 0.2426 0.3332 0.2860 0.1674 0.3699 0.0162 0.0684 0.1941 0.7467 0.2502 0.7494 0.6179 0.7437 0.5727 0.7496 0.5450 0.1501 0.7008 0.7268 0.6827 0.1983 0.6573 0.1145 0.1381 0.4062 0.1319 0.2090 0.2495 0.3681 0.1703 0.2472 0.8547 0.8557 0.8559 0.8276 0.8296 0.8337 0.8098 0.7174 0.7860 0.8507 0.8571 0.8568 0.7788 0.7643 0.8361 0.5943 0.8503 0.6634 0.8154 0.5553 0.6381 0.8026 0.8329 0.7765 0.8291 0.5176 0.3258 0.7061 0.0813 0.6518 0.6491 0.7325 0.4026 0.6092 0.5142 0.7588 0.6113 0.6028 0.8479 0.4699 0.4639 0.8505 0.8395 0.6115 0.3736 0.6366 0.6079 0.2017 0.4010 0.8571 0.7273 0.6773 0.5490 0.5335 0.4806 0.8570 0.7260 0.6512 0.4148 0.5433 0.6050 0.8051 0.5256 0.2389 0.7472 0.6688 0.8251 0.5891 0.6515 0.4374 0.6321 0.1598 0.5997 0.7101 0.8571 0.7315 0.6321 0.6731 0.4180 0.6768 0.8463 0.7536 0.8164 0.8553 0.4981 0.4286 0.1649 0.3140 0.6126 0.7238 0.8357 0.5473 0.2137 0.8192 0.5283 0.5127 0.8481 0.7698 0.4087 0.2285 0.2659 0.4950 0.5249 0.5358 0.6506 0.5784 0.4181 0.2714 0.2889 0.5340 0.8533 0.8126 0.2754 0.8435 0.5961 0.4088 0.7964 0.3180 0.2922 0.5579 0.2443 0.4190 0.6454 0.7078 0.7124 0.7269 0.4714 0.4544 0.4084 0.8571 0.6945 0.5328 0.3569 0.4126 0.4222 0.8311 0.8561 0.4251 0.8543 0.8031 0.4775 0.5593 0.4013 0.6589 0.7530 0.5220 0.3513 0.4650 0.5976 0.7758 0.8121 0.5596 0.3905 0.4999 0.4448 0.2868 0.5400 0.0319 0.1281 0.3251 0.8550 0.4003 0.8568 0.7638 0.8530 0.7283 0.8569 0.7055 0.2610 0.8241 0.8418 0.8115 0.3310 0.7932 0.2054 0.2427 0.5777 0.2330 0.3457 0.3994 0.5381 0.2910 0.3964 298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 6 6 1 6 8 7 6 6 6 6 6 6 7 6 8 6 16 6 1 7 7 6 7 6 6 6 6 6 6 6 6 6 6 6 6 6 7 1 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 1.00783 12.00000 15.99491 14.00307 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 12.00000 15.99491 12.00000 31.97207 12.00000 1.00783 14.00307 14.00307 12.00000 14.00307 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 1.00783 12.00000 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 11518.6746 39833.7697 47818.9042 0.99997 0.00783 -0.00077 -0.00783 0.99995 -0.00674 0.00072 0.00674 0.99998 1 0.00752 0.00217 0.00181 0.15668 0.04531 0.03774 12.45 13.55 19.70 28.35 35.65 42.84 48.36 53.98 75.39 80.94 85.58 105.77 130.00 138.65 150.30 176.49 207.05 236.03 264.13 281.15 289.59 323.81 342.60 364.06 368.67 376.45 442.88 451.52 473.36 488.25 527.70 558.73 601.91 606.44 615.67 638.73 641.91 659.10 667.31 669.16 722.90 729.38 760.48 772.73 774.86 793.59 834.03 845.37 847.60 860.65 912.19 953.89 956.79 970.60 978.65 986.59 1000.73 1036.84 1080.50 1107.57 1111.36 1131.87 1149.85 1157.35 1193.16 1218.74 1238.26 1247.65 1267.72 1277.82 1328.17 1337.99 1368.53 1370.34 1380.07 1384.51 1390.63 1427.14 1461.36 1508.12 1508.56 1513.66 1518.40 1522.45 1540.05 1569.19 1573.23 1590.14 1600.20 1604.81 1609.14 1611.96 1621.23 1625.37 1645.66 1653.21 1663.90 1678.67 1680.91 1700.00 1712.45 1720.63 1741.34 1742.99 1758.78 1785.71 1811.08 1843.03 1849.38 1858.38 1863.24 1889.41 1890.21 1918.35 1923.95 1951.68 1970.28 1998.34 2001.84 2021.26 2035.68 2060.52 2102.91 2111.45 2138.67 2156.46 2165.31 2168.77 2210.45 2233.50 2255.27 2257.65 2276.04 2277.77 2293.74 2313.65 2321.51 2325.59 2343.10 2344.68 2355.70 2355.86 2404.22 2418.65 2450.04 2495.22 2501.59 2539.48 2566.18 2589.95 2592.77 2623.90 2625.69 2669.26 2836.14 2856.11 4585.96 4627.90 4641.51 4665.83 4713.44 4722.84 4732.70 4752.82 4788.81 4806.83 4811.91 4830.16 4840.54 4860.57 4875.33 4878.67 4891.58 4902.78 4905.07 4910.94 4939.27 4958.58 4984.97 5505.90 5571.37 5576.19 5587.17 0.544053 0.575052 0.575996 0.473446 -1911.331010 -1911.300012 -1911.299068 -1911.401617 3.439510D-04 MUNgauss RevisionA2.0 retrievium 16-Feb-2020 DUDE C[C@H](C(=O)Nc1ccc(cc1)NC(=O)C)S[C@H]2NN=C(N2c3ccccc3)C4=c5ccccc5=[NH+]C4 C39933412 RHF 6-31G(d) (6D,10F) C1 499.191621 |X|Y|Z| 142.993253 73.441944 33.994400 70.939648 30 6 7 16 24 5 1 |36.858105| |12.475258|36.858105| |8.847701|17.617134|0.500000| |7.580213|12.440124|0.244714|36.858105| |6.818983|8.025307|0.164646|15.932256|73.516695| |5.199216|7.839751|0.209230|14.068013|14.974051|53.358707| |3.870137|5.009317|0.134468|7.686158|11.719065|18.272414|36.858105| |3.226573|3.979364|0.113773|5.236431|8.152343|10.764133|13.749273|36.858105| |2.655284|3.125057|0.087877|3.938337|6.572990|7.038488|7.928131|13.789112|36.858105| |2.505679|2.895246|0.078788|3.686504|6.504032|6.153215|6.813165|7.908417|13.708937|36.858105| |2.778757|3.233647|0.084903|4.316377|7.971453|6.963682|7.909216|6.891644|7.962734|13.692489|36.858105| |3.454077|4.213480|0.107623|6.241975|11.417917|10.529782|13.734851|7.979059|6.907833|7.913614|13.768869|36.858105| |2.121314|2.385860|0.065226|2.903755|5.185316|4.614803|4.533915|5.188484|7.959558|13.538341|7.724398|5.122798|53.358707| |1.931138|2.142736|0.057971|2.564398|4.665370|3.928221|3.666220|3.896642|5.159715|7.624740|6.255812|4.309862|18.955455|36.858105| |1.966073|2.180566|0.058174|2.620801|4.847776|3.937940|3.629686|3.630164|4.478702|6.547191|6.572554|4.510445|11.456787|15.931124|73.516695| |1.689284|1.846654|0.050400|2.150186|3.891417|3.246839|2.899956|3.133140|3.996711|5.031694|4.211596|3.233375|10.731098|12.580981|14.236455|36.858105| |6.866397|10.363419|0.221915|6.961856|10.060051|7.538344|4.070104|3.302160|2.723535|2.601019|2.933760|3.704952|2.978694|2.014904|3.708267|1.742758|388.023441| |4.770975|6.678759|0.198826|5.003346|7.125286|6.553950|3.681009|3.201282|2.646634|2.457258|2.656811|3.226257|2.847952|1.914871|3.473775|1.676952|75.047839|36.858105| |3.932204|5.052369|0.142211|4.126056|6.212105|5.442045|3.246904|2.852034|2.428430|2.295893|2.488277|2.957008|2.698609|1.839920|3.363217|1.618284|58.514668|17.500480|0.500000| |4.185269|6.038444|0.197549|5.148407|7.055686|7.765792|4.339782|3.880763|3.113045|2.795757|2.955009|3.596980|3.191938|2.105581|3.771769|1.833456|49.293479|13.086294|0.249123|53.358707| |3.590730|4.690740|0.160684|4.010360|5.727915|6.052367|3.599585|3.446390|2.832335|2.503907|2.561425|2.995572|2.924061|1.927510|3.407851|1.709656|34.975863|8.251568|0.183266|19.003058|53.358707| |3.756434|4.645873|0.159868|3.708111|5.408579|5.223810|3.099820|2.936605|2.455541|2.206316|2.273722|2.643979|2.609138|1.737788|3.083344|1.554649|35.188352|8.414066|0.185630|12.259152|20.511532|36.858105| |4.575071|5.666761|0.185986|4.124143|6.029596|5.398144|3.115183|2.828913|2.366642|2.172748|2.295765|2.714272|2.559839|1.719971|3.087205|1.530029|48.411027|12.960436|0.251393|11.573955|11.592729|13.631592|53.358707| |3.945098|4.370833|0.131567|3.323329|5.130968|4.250553|2.562606|2.342951|2.017149|1.885199|1.994840|2.311052|2.260022|1.539894|2.777027|1.383210|38.695868|7.707447|0.204243|7.305393|7.431292|7.744125|18.057192|36.858105| |3.088085|3.407809|0.100749|2.774761|4.372769|3.644751|2.276343|2.112509|1.853980|1.743856|1.832956|2.084423|2.116131|1.453450|2.623914|1.314643|30.123286|5.888638|0.181080|6.210385|6.556673|6.301232|10.544034|13.702800|36.858105| |2.708804|2.859708|0.082529|2.382262|3.853723|3.099251|1.975185|1.840585|1.640179|1.558278|1.637681|1.839157|1.911944|1.324504|2.396265|1.206758|24.630937|4.248447|0.129856|4.687102|4.861372|4.374588|6.964061|7.929810|13.754049|36.858105| |2.804719|2.832098|0.080462|2.336783|3.834222|2.974932|1.893628|1.755816|1.566878|1.495359|1.578171|1.773286|1.837474|1.275416|2.310207|1.163615|23.851404|3.782550|0.110842|4.155770|4.216487|3.755158|6.161997|6.871993|7.935094|13.737293|36.858105| |3.399882|3.317510|0.093768|2.638138|4.317024|3.278997|2.049729|1.881891|1.662034|1.582123|1.678703|1.907520|1.929880|1.333097|2.413704|1.210717|27.519213|4.160295|0.115752|4.442736|4.424055|4.001449|6.999913|7.943316|6.872796|7.935892|13.748256|36.858105| |4.261051|4.275154|0.123655|3.203931|5.086627|3.946579|2.392108|2.175480|1.885528|1.777105|1.890430|2.184785|2.140125|1.464470|2.646012|1.319504|35.887518|5.652688|0.147422|5.669869|5.586595|5.318325|10.667244|13.749814|7.921373|6.863798|7.927909|13.741529|36.858105| |3.177217|3.640854|0.122358|3.013755|4.542215|4.241615|2.621766|2.563485|2.193259|1.966334|1.992634|2.261035|2.366713|1.580433|2.782933|1.434435|26.102434|5.167628|0.125897|7.397116|10.960537|13.060021|10.247603|6.154200|5.528730|4.174608|3.628528|3.785058|4.712682|36.858105| |2.646044|3.000208|0.098276|2.616461|4.005767|3.776545|2.421738|2.437980|2.124409|1.893444|1.885843|2.097885|2.306446|1.539646|2.691246|1.410508|21.276653|3.989013|0.101541|6.037604|8.755191|7.521939|6.825955|4.369690|4.281532|3.469654|3.019528|3.047086|3.556771|13.997388|36.858105| 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|2.363314|2.502083|0.071977|2.141978|3.492382|2.821360|1.828482|1.717824|1.546871|1.474748|1.543065|1.714645|1.822938|1.268752|2.295608|1.161548|21.278551|3.626519|0.112463|4.181362|4.367908|3.774805|5.649384|5.643963|8.928747|17.728674|8.905721|5.643965|4.948127|3.685883|3.226033|2.863190|2.513757|2.414794|2.586363|3.009718|4.359134|0.082960|3.699048|0.059225|0.062494|0.071926|0.061552|0.049122|0.041010|0.040868|0.048949|0.036061|0.032227|0.031258|0.031162|0.079344|0.215518|0.500000| |2.478131|2.468854|0.069560|2.083528|3.465926|2.658791|1.716790|1.599553|1.441458|1.383019|1.457040|1.622172|1.711952|1.194488|2.165209|1.095315|20.392903|3.133802|0.091911|3.552815|3.599491|3.110694|4.908695|4.952522|5.646277|8.914462|17.730724|8.915817|5.642578|3.063049|2.641331|2.303499|2.060901|2.036419|2.229291|2.577337|3.930111|0.078060|3.352334|0.062007|0.066419|0.077858|0.056866|0.045541|0.038109|0.038798|0.046768|0.033846|0.030193|0.029487|0.029619|0.066616|0.124163|0.214774|0.500000| |3.321704|3.101939|0.086303|2.498476|4.163150|3.072695|1.936714|1.778541|1.579769|1.511100|1.605331|1.816113|1.850739|1.282214|2.322960|1.167806|24.796324|3.529799|0.096986|3.882437|3.834384|3.365152|5.683168|5.652475|4.953034|5.644583|8.913048|17.731254|8.929188|3.233011|2.673973|2.282530|2.018220|1.994779|2.208286|2.604977|4.107355|0.081722|3.689842|0.081512|0.088332|0.111500|0.065121|0.050689|0.041438|0.042537|0.052754|0.036511|0.032017|0.031271|0.031762|0.070790|0.107501|0.124087|0.214873|0.500000| |5.354360|5.018522|0.143801|3.581530|5.676714|4.276427|2.547746|2.296156|1.972535|1.855443|1.982227|2.312778|2.221336|1.513444|2.731643|1.359255|38.960381|5.497421|0.134533|5.634625|5.418398|4.998658|9.866934|8.947945|5.647020|4.949761|5.636687|8.886309|17.748763|4.405108|3.356484|2.788876|2.371085|2.287059|2.527595|3.107970|4.913011|0.092927|4.897260|0.122923|0.129654|0.202140|0.092333|0.066141|0.051133|0.051551|0.067066|0.043692|0.037252|0.036050|0.036928|0.096450|0.124155|0.107485|0.123968|0.214466|0.500000| 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